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You would like to know the actual structure of metals and what is important in iron production?°

Here you can find out what materials actually are and why materials technology is important. You will learn step by step about the structure of metals, see how the combination of atoms forms the crystal lattice and how the structure is created from this. You will also learn which properties metals have. Finally, you will go through the process of extracting iron and producing steel and see what needs to be taken into account.

   

You will learn
What are materials and why is material technology important?

How are metals structured? Atoms - crystalline lattices - structure

What properties have metals?

How is pig iron won?

What should be considered in steel making? 
  

Materials history

Throughout history, we humans have needed materials for various everyday purposes. They have impacted different cultures and different eras have been named after them.

Werkstoffe historie

Material subdivisions

Materials can be split into metals or non-metals. Steel and cast iron are among the most commonly used materials worldwide.

Werkstoff Unterteilung

Materials technology and its importance

The purpose for which a particular material is used depends on its properties. These can be divided into different categories.

°°

Various scientific material technology methods are used to place materials into different categories and properties in the first place.

°°

Materials technology deals with extraction and use of materials and examines their various properties. This enables materials to be used properly, new materials to be developed and existing ones to be improved.

°°

Knowledge of the internal structure of materials is a prerequisite for analysing their properties. Only when you know what components a material is made up of and how these work are you able to gain new insights for further development.

Werkstofftechnik

Structure of metals

Aufbau von Metalle

Steel and cast iron possess many properties that make them among the most widely used materials in the world. When using them, we usually work with the finished product. But what is metal actually made up of?

°°

Many things are not visible to the naked eye. But with a microscope, you can see even the smallest components. 

Metals under the microscope

The positive charged particles of metal atoms are always arranged at fixed distances to one another, forming the crystalline lattice. They emit negative electrons, which surround the crystalline lattice as a so-called electron cloud. The electrons can move freely within this cloud, but cannot leave it.

The attraction of the positive and negative charges creates a strong metal bond. This ensures an extremely stable bond of the metal atoms and in turn the strength of the metal.

Summary of materials

You now know that materials have always played an important role and have characterised many eras and cultures. You have learnt that materials can generally be divided into metals and non-metals and can have different properties.°

You have also have learnt that materials technology is used to investigate the properties of materials so that new ones can be developed and existing ones improved. Finally, you have seen that metals are made up of a structure, crystal lattice and finally metal atoms, whose composition influences the metallic properties.

  

YOU HAVE°LEARNT°
Materials have always played an important role for humanity and have impacted many eras and cultures. 

Materials can be split into metals or non-metals. 

Material technology analyses the various properties of materials in order to develop new or improve existing materials. 

Metals are made up of a structure, crystalline lattice and metal atoms. 

These components influence metallic properties. 
 

Metals - structure and properties
How do metals conduct and how can they be deformed? 

What types of°crystal lattice°are there? 

Which°grid construction errors°can occur? 

How is a structure built? 

What are alloys and which types are there? 

What are status diagrams of alloys? 
 

  

Structure of metals

Now we will take a look at the exact structure of metals and their properties. To do this, you will first find out how metals conduct and can be deformed. You will get to know different types of crystalline lattice and see what kind of lattice defects can occur. Then we will take a closer look at the structure of metals and get to understand what happens with alloys. Finally, you will learn what types of alloys there are and how to read corresponding parametric diagrams.  

Conductivity of metals

Metalle sind leifähig

As metals are conductive, they find use for various purposes in everyday life. The structure of the crystal lattice makes it easier to understand the electrical conductivity.

Deformation of metals

Besides being electrically conductive, metals can also be deformed. They can be deformed°elastically or plastically.

Let's take another look at the atomic level in the crystal lattice. When force is applied to sheet metal, the metal atoms are displaced slightly in the lattice, but then spring back. By a°lead rod°however, the displaced positions in the crystal lattice remain after the force is removed, thus causing a permanent deformation.

Metalle sind verformbar

Crystal lattice of metals

You have already learnt that the metal atoms have one thing in common - they are arranged in crystal lattices. However, the crystal lattices are not always the same. Depending on the type of metal, the geometric arrangements of the atoms in the crystal lattice differ. 

° °

Here you can see the three key types of crystal lattice once again with their connecting lines. These always run from the centre of the atom and so form an individual arrangement.

    Three key crystal lattice types

    BODY CENTRED CUBIC (BCC)°

     KUBISCH-RAUMZENTRIERT (KRZ)

    The cube has an enclosed metal atom at the centre. Since it is only loosely packed, there is no stacking sequence.°

    Relatively wide spacing between the atoms permits additional foreign atoms to be incorporated.°

    ° °°

    FACE-CENTRED CUBIC (FCC)°

    KUBISCH-FLÄCHENZENTRIERT (KFZ)

    The cube consists of of 8 atoms, one in each corner of the cube and one atom in the centre of each side.°

    The atoms are arranged in three stacks (ABC) and thus form the densest spherical packing.°

    A disturbed stacking sequence leads to stacking faults into which alloying elements can be deposited.°This results in other properties. 


       

    HEXAGONAL-CLOSE-PACKED (HCP)°

    HEXAGONAL-DICHTEST GEPACKT (HDR)

    The metal atoms are arranged in an hexagonal prism, with one atom at the centre of each base surface.°3 atoms are inside the prism.°

    The stacking sequence is ABA and thus forms the densest spherical packing.°

    Wide lattice gaps provide space for foreign atoms.°

    Less cold formable than metals with fcc lattices. 

    Grid structure errors

    Metals are not perfect crystals, they have lattice defects. Lattice defects can be assigned to three dimensions, depending on type and size. The first dimension is the zero-dimensional defect. These correspond to a lattice point and can be further subdivided.

    The zero-dimensional defects generally have no negative effects on the properties of metallic materials, but even enable important heat treatments.

    One-dimensional error

    There are also one-dimensional defects, so-called line defects. If a half-plane is inserted into the regular crystalline lattice, the line is faulty and a stage dislocation forms. Dislocations can move and consequently cause plastic deformability of metals.

    eindimensionalen Fehler

    zweidimensionalen Fehlern

    Two-dimensional errors 

    Two-dimensional errors result in stacking errors° ° °of the regular layer sequence. Stacking faults are caused by° °crystallisation or the collapse of a° °void cluster. Two-dimensional lattice defects have an° °influence on the tensile strength of a metal. 

    Structure

    You have already learned that metals consist of many regularly shaped grains, which form the structure. The structure is not visible to the naked eye. But with the aid of a metallographic micrograph, the structure can be made visible under a metal microscope.°

    The micrograph shows the grain size and the grain boundaries of a metal. The grain size ranges from fine to coarse and can be adjusted by targeted treatments. Grain boundaries represent interruptions in the atomic arrangement of the grains and are part of the two-dimensional lattice defects mentioned. These form during crystallisation for example. 

    Gefüge

    Fine-grained metals have better mechanical properties compared to coarse-grained metals, as there are more grain boundaries. An increase in grain boundary improves toughness. °However, undesirable creep processes occur at increased temperatures.

    Grain forms

    In addition to the commonality of grain size and grain boundaries, grain forms vary depending on the metal and the type of crystal lattice.

    GLOBULAR GRAINSGLOBULARE KÖRNER

    Round grains, e.g. pure iron°

    POLYHEDRAL GRAINS POLYEDRISCHE KÖRNER

    Grains in polygonal shape, e.g. iron with°austenite structure

    DENDRITIC GRAINS DENDRITISCHE KÖRNERNeedle-like grains, e.g. hardened steel°

    LAMELLAR-LIKE STRUCTURE LAMELLENARTIGE GEFÜGELamellar crystals, e.g. lamellar graphite in grey cast iron

    Alloys

    You have already learnt that metals are not perfect crystals, but have deliberate lattice defects. Of all the metals in the periodic table, only the precious metal gold occurs in its pure form. All other metallic materials are metal mixtures and are called alloys.

    The alloying process involves intentionally inserting one or more metallic elements into the crystal lattice of a metal in order to achieve desired changes in properties.

    Legierungen

    Legierungsvorgang

    As the temperature decreases after the alloying process, the molten metal begins to cool and, during solidification forms a new metal mixture with the alloying element.

    Types of°alloys

    The alloying elements can be embedded into the base metal in different ways and form two different structures in solid state.

    Solid solution alloy

    Mischkristall-Legierung

    Crystal mixture alloy

    Kristallgemisch-Legierung

    Solid solution alloys in the liquid state are completely soluble with one another. The metals distribute evenly during solidification. They are stronger than pure base metals, but are well formable. Crystal mixtures are also soluble in one other in liquid state; in the solid state the metals then aggregate separately.

    Status diagrams of°alloys

    To research and further develop the properties of alloys, their state diagrams are analysed. In general, status diagrams show the aggregate status of pure metals. For this purpose the inflexion point in the cooling or heating curve is used. 

    Zustandsdiagramme von Legierungen

    By alloys, the temperature of the second metal and the mixing ratio within the alloy is also taken into account. When all inflection points are transferred and the temperature points connected, the status diagram for the alloy is given.°

    Solid solutions and crystal mixtures have different status diagrams. Solid solutions such as copper and nickel are characterised by complete solubility in the liquid and solid state.

       

    Zustandsdiagramme von Kristallgemische

    The status diagram for crystal mixtures such as lead and tin looks different. This is characterised by the complete solubility in the liquid state and insolubility in the solid state.

       

    YOU HAVE°LEARNT°
    Electrical current is the flow of electrons.

    Metals can be deformed elastically (reversible) or plastically (irreversible).

    The three key crystal lattice types are: face-centred cubic (fcc), body-centred cubic (bcc), hexagonal close-packed (hcp)

    Metals are not perfect crystals, but have lattice defects:°Zero-dimensional defects,°one-dimensional defects,°two-dimensional defects

    The structure is made up a multitude of regularly shaped grains.

    In alloys, metallic elements are intentionally inserted into the crystal lattice.°This results in solid solution crystals and crystal mixtures.

    Status diagrams show the aggregate states of alloys. 

    Extragerea fontei brute

    În ultima secțiune, vom analiza mai întâi modul în care este extrasă fonta brută și care sunt etapele importante în procesul de extracție. Apoi veți afla mai multe despre diferitele procese utilizate pentru a produce oțel din fontă brută. În final, veți vedea diferitele modalități de post-tratare și de turnare a oțelului. 

    După cum ați învățat, oțelul este unul dintre cele mai utilizate materiale din lume. Componenta principală este fierul. Fierul apare în mod natural sub formă de minereu de fier, un compus de fier și oxigen. Pentru a produce oțel, fierul trebuie mai întâi extras prin intermediul unui proces de reducere. 

    Două procese de reducere sunt utilizate în procesul de extracție a fontei brute. Aici puteți vedea o prezentare generală a ambelor procese. 

    Gewinnung von Roheisen

    Producția de oțel

    După extragerea fontei brute sau a fierului burete solid, se folosesc așa-numitele „procese proaspete” pentru a produce oțelul. Vă puteți imagina ce se întâmplă în timpul procesului de afinare? 

    În procesul de purjare cu oxigen , fonta brută topită este introdusă într-un convertizor împreună cu deșeuri de oțel și aditivi. Un tub răcit cu apă suflă oxigen în recipient și determină o reacție chimică cu elementele însoțitoare ale fierului. Carbonul din fonta brută arde, iar varul leagă elementele însoțitoare ale fierului. Oțelul și zgura sunt apoi turnate.

     Sauerstoffaufblas-Verfahren

    Procedeul cu cuptor cu arc electric este utilizat pentru fabricarea oțelurilor înalt aliate. În acest proces, o cuvă de topire este umplută cu fontă brută și alte componente. Electrozii de carbon sunt coborâți pe umplutură și se aprinde un arc electric. În timpul fazei de topire, carbonul rămas și substanțele însoțitoare sunt arse. Oțelul și zgura sunt apoi turnate.

    Elektrolichtbogenofen-Verfahren

    După producția de oțel, rămân adesea componente nedorite. Pentru a produce oțeluri de calitate, acestea sunt îndepărtate prin post-tratare suplimentară. Aici puteți vedea cele mai importante proceduri și descrierile acestora. Activați procedurile pentru mai multe detalii. 

    Tratarea ulterioară a materialului turnat

    DEZOXIDARE 
    Elementele colectează oxigenul eliberat atunci când topitura se solidifică. 
    Acest lucru previne formarea de cavități cu bule de gaz. 
    DESOXIDATION

    Degazare în vid

    Retopirea oțelului lichid favorizează eliminarea gazelor reziduale. 
    În caz contrar, acestea vor provoca tensiuni și mici fisuri în oțel pe termen lung.

    Vakuum-Entgasung

    Procesul de retopire

    Blocul de oțel inoxidabil este conectat ca electrod într-o formă de oțel (cochilă). Un arc electric topește blocul de oțel într-o baie de zgură. 
    Oțelul topit se scurge printr-o zgură de curățare, care colectează ultimele impurități.

    Umschmelz-verfahren

    Tratarea gazului de spălare

    Gazul de spălare elimină impuritățile.

    Spülgasbehandlung

      

    Odată ce tratarea ulterioară s-a încheiat, oțelul topit este turnat și dobândește astfel forma inițială pentru prelucrarea ulterioară. Aici sunt utilizate două metode. În turnarea continuă, oțelul curge în mod continuu într-o cochilă de trecere, răcită cu apă. La final rezultă un semifabricat continuu de oțel, care mai trebuie doar laminat la dimensiunea finală.

    Strangguss Verfahren

       

    Pentru blocuri mari de oțel se utilizează turnarea în bloc în cochilă. În acest proces, oțelul lichid curge în forme metalice. După solidificare, cochilele sunt scoase în timp ce sunt încă încinse. De îndată ce blocurile de oțel s-au răcit, acestea pot fi utilizate ca piese forjate sau profiluri laminate. 

       

    Kokillen-Blockguss Verfahren

       

    Rezumat

    Acum știți că fierul trebuie mai întâi extras din minereul de fier și că acest lucru se face fie într-un furnal înalt, fie prin reducere directă. De asemenea, ați învățat că în producția de oțel sunt utilizate diverse procese de rafinare pentru a reduce conținutul de carbon și a elimina produsele secundare. 

    În cele din urmă, ați învățat despre diferite procese de tratare a oțelului. Acestea sunt utilizate pentru a elimina orice componente nedorite rămase. Acum sunteți familiarizați și cu două procese de turnare care pregătesc oțelul pentru prelucrarea ulterioară. 

       

    AȚI AFLAT 
    Fierul este extras din minereu de fier (în furnale sau prin reducere directă). 

    Procedeele de afinare sunt utilizate pentru a reduce carbonul rezidual și pentru a elimina elementele însoțitoare.

    Post-tratamentul oțelului este utilizat pentru a elimina orice componente nedorite rămase.

    Turnarea oțelului servește la pregătirea oțelului pentru prelucrarea ulterioară.